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lithium monoxide anion wikipedia jump to content main menu main menu move to sidebar hide navigation main page contents current events random article about wikipedia contact us contribute help learn to edit community portal recent changes upload file special pages search search appearance donate create account log in personal tools donate create account log in contents move to sidebar hide top 1 synthesis of the lithium monoxide anion 2 references 3 see also toggle the table of contents lithium monoxide anion 4 languages 한국어 தமிழ் اردو 中文 edit links article talk english read edit view history tools tools move to sidebar hide actions read edit view history general what links here related changes upload file permanent link page information cite this page get shortened url switch to legacy parser print export download as pdf printable version in other projects wikidata item appearance move to sidebar hide from wikipedia the free encyclopedia lithium monoxide anion names iupac name lithium monoxide anion other names lithate identifiers cas number 64538 53 0 1 3d model jsmol interactive image comptox dashboard epa dtxsid901337186 inchi inchi 1s li o q 1 key ixzjkksrifxcqd uhfffaoysa n smiles li o properties chemical formula li o molar mass 22 94 g mol 1 conjugate acid lithium hydroxide hazards occupational safety and health ohs osh main hazards extremely corrosive related compounds related bases methyl anion diethynylbenzene dianions except where otherwise noted data are given for materials in their standard state at 25 c 77 f 100 kpa n verify what is y n infobox references chemical compound lithium monoxide anion lio is a superbase existing in the gas phase it was the strongest known base until 2008 when the isomeric diethynylbenzene dianions were determined to have a higher proton affinity the methanide ion ch 3 was the strongest known base before lithium monoxide anion was discovered 2 lio has a proton affinity of 1782 kj mol 3 synthesis of the lithium monoxide anion edit the anion is prepared in a mass spectrometer by successive decarboxylation and decarbonylation of lithium oxalate anion under collision induced dissociation cid conditions lio c o co 2 lio c o co 2 lio c o lio co the above method to synthesize the lithium monoxide anion is inefficient and difficult to carry out the required ion rapidly reacts with traces of moisture and molecular oxygen present in the air the reaction is further intensified by the high pressure argon that is introduced into the instrument to carry out the cid step 4 references edit lithium oxide anion webbook nist gov poad berwyck l j reed nicholas d hansen christopher s trevitt adam j blanksby stephen j mackay emily g sherburn michael s chan bun radom leo 2016 preparation of an ion with the highest calculated proton affinity ortho diethynylbenzene dianion chemical science 7 9 6245 6250 doi 10 1039 c6sc01726f pmc 6024202 pmid 30034765 srivastava ambrish kumar misra neeraj 6 february 2016 oli 3 o anion designing the strongest base to date using oli 3 superalkali chemical physics letters 648 152 155 bibcode 2016cpl 648 152s doi 10 1016 j cplett 2016 02 010 tian zhixin chan bun sullivan michael b radom leo kass steven r 2008 06 03 lithium monoxide anion a ground state triplet with the strongest base to date proceedings of the national academy of sciences of the united states of america 105 22 7647 7651 bibcode 2008pnas 105 7647t doi 10 1073 pnas 0801393105 issn 0027 8424 pmc 2409378 pmid 18511563 see also edit lithium oxide v t e lithium compounds list compounds with noble gases lihe hlihe hypothetical lifheo hypothetical lihe 2 hypothetical heo lif 2 hypothetical la 2 3 x li 3x tio 3 he hypothetical compounds with halogens flibe flinak liat hypothetical libr libro libro 2 libro 3 libro 4 licl liclo liclo 2 liclo 3 liclo 4 lif li 2 f lifo lii liio liio 2 liio 3 liio 4 oxides and hydroxides lio lio 2 lio 3 li 2 o li 2 o 2 lioh compounds with chalcogens licf 3 so 3 lihso 3 lihso 4 li 2 po li 2 s li 2 se li 2 seo 3 li 2 seo 4 li 2 te lite 3 li 2 teo 3 li 2 teo 4 compounds with pnictogens li 1 x al x ge 2 x po 4 3 lial 1 x ti 2 x po 4 3 li 3 sb lias liasf 6 li 3 aso 4 lifepo 4 lige 2 po 4 3 lih 2 aso 4 li 2 haso 4 li 2 hpo 3 li 2 hpo 4 li 3 po 3 li 3 po 4 lih 2 po 3 lih 2 po 4 lin 3 li 3 n linh 2 li 2 nh lino 2 lino 3 li 2 n 2 o 2 li 2 napo 3 linano 2 li 3 p lipf 6 li 3 po 4 li sbf 6 liti 2 po 4 3 lizr 2 po 4 3 compounds with group 14 elements li 2 c 2 li 2 co 3 li 2 gef 6 li 2 geo 3 lihco 3 li 3 h co 3 2 lisi li 2 sif 6 li 2 sio 3 li 2 si 2 o 5 li 4 sio 4 li 2 snf 6 compounds with group 13 elements cslib 6 o 10 lialcl 4 lialf 4 li 3 alf 6 lialh 4 lialo 2 lib c 2 o 4 2 lib c 6 f 5 4 libf 4 libh 4 libo 2 lib 3 o 5 li 2 b 4 o 7 libsi 2 ligah 4 compounds with transition metals li aucl 4 licoo 2 li 2 cro 4 li 2 cr 2 o 7 li 2 iro 3 li 7 la 3 zr 2 o 12 limn 2 o 4 li 2 moo 4 li 0 9 mo 6 o 17 linbo 3 li 2 nbo 3 li 2 pto 3 li 2 ruo 3 litao 3 li 2 tif 6 li 2 tio 3 li 4 ti 5 o 12 livo 3 li 3 v 2 po 4 3 liwf 6 li 2 wo 4 li 2 zrf 6 li 2 zro 3 organic soaps hemolithin extraterrestrial protein organolithium reagents gilman reagent ch 3 cooli c 4 h 6 lino 4 lic 2 f 6 no 4 s 2 lin sime 3 2 li 3 c 6 h 5 o 7 c 5 h 5 li lin c 3 h 7 2 c 6 h 5 2 pli c 18 h 35 lio 3 c 6 h 13 li c 4 h 9 li ch 3 chlich 2 ch 3 ch 3 3 cli c 12 h 28 bli ch 3 li li c 10 h 8 c 5 h 11 li c 5 h 3 lin 2 o 4 c 6 h 5 li lic 2 ch 3 c 7 h 5 lio 3 lio 2 c ch 2 16 ch 3 c 4 h 5 lio 4 liet 3 bh lioc ch 3 3 c 9 h 18 lin lic 2 h 3 lic 11 h 23 coo ch 3 ch oh cooli lic 2 h 2 clo 2 lic 2 h 3 io 2 li ch 3 2 n licho 2 lich 3 o lic 2 h 5 o li 2 c 2 o 4 other compounds li 2 li x be y hypothetical licn li 2 cn 2 licno lih lina liscn liyf 4 neodymium doped minerals amblygonite berezanskite brannockite cryolithionite darapiosite darrellhenryite elbaite fluorine elbaite fluor liddicoatite emeleusite eucryptite faizievite hectorite hsianghualite jadarite kunzite lavinskyite lepidolite lithiophilite lithiophosphate manandonite manganoneptunite nambulite neptunite olympite petalite pezzottaite rossmanite saliotite sogdianite spodumene sugilite tiptopite tourmaline triphylite zabuyelite zektzerite zinnwaldite other li related aluminium lithium alloys heteroatom promoted lateral lithiation lb buffer lithium atom lithium medication lithium cocrystal lini x co y al z o 2 lini x mn y co z o 2 lithium soap lithium triangle lucifer yellow magnesium lithium alloys nasicon environmentally friendly red light flare retrieved from https en wikipedia org w index php title lithium_monoxide_anion oldid 1260089779 categories superbases lithium compounds oxyanions hidden categories chemicals without a pubchem cid articles without inchi source chemical pages without chemspiderid articles without ebi source articles without kegg source articles without unii source articles containing unverified chemical infoboxes chembox articles without image chembox image size set articles with short description short description matches 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