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pd metalated conjugated nanoporous polycarbazoles for additive free cyanation of aryl halides boosting catalytic efficiency through spatial modulation oak ridge national lab skip to content explore close menu explore atoms to applications future of computing nuclear solutions resilient energy systems national security careers news directorates user facilities major projects education and workforce about us back our strategy biotechnology materials neutrons manufacturing our strategy super intelligence autonomous science quantum our strategy isotopes fission fusion our strategy buildings grid regional resilience transportation overview leadership operations partnerships explore find the information people and opportunities you re looking for learn about ornl s role careers staff directory come see us our strategy accelerate innovation ensuring u s leadership in the development manufacture and deployment of materials chemistries and components for energy and security applications explore atoms to applications biotechnology leading the biotechnology revolution to ensure american energy food security global competitiveness and human health explore biotech at ornl mengjun shu mapping tree resilience with ai biological data read the full story center for bioenergy innovation strengthens leadership with new team leads read the full story samuels receives health physics society s elda e anderson award read the full story q a with melissa cregger from field to factory with precision crops read the full story materials discovering and designing the materials that power u s energy national security and economic competitiveness explore materials at ornl department of energy selects ornl to lead nine genesis mission projects read the full story ornl s david radford builds tools to explore deep questions read the full story new mineral named for ornl researcher tyler spano read the full story operations workforce powers ornl s autonomous science future read the full story neutrons using world leading neutron science to reveal the structure and behavior of materials explore neutrons at ornl neutrons reveal how friction stir welding could strengthen steel read the full story ornl scientists pinpoint new ways to synthesize power source read the full story ornl s jason newby advances neutrino research frontiers read the full story ornl researchers showcase ai driven science at national expo read the full story manufacturing integrating advanced materials artificial intelligence and digital engineering to strengthen u s competitiveness energy security and national defense explore manufacturing at ornl ornl launches national cement and concrete innovation hub read the full story doe expands stable isotope production capabilities at ornl read the full story hassen named fellow of the american society for nondestructive testing read the full story ornl earns five doe transportation technologies office awards read the full story our strategy integration creating a smart post exascale ecosystem that integrates hpc ai and quantum for open science and national security explore the future of computing si applying si to accelerate discovery strengthen security and transform complex systems explore si at ornl doe expands stable isotope production capabilities at oak ridge national laboratory read the full story ornl deploys new iqm quantum computer read the full story streamlining arm data access with ai ready infrastructure read the full story ornl and partners achieve first known computations of fusion materials on a quantum computer read the full story autonomous science combining ai automation and advanced scientific tools to help researchers accelerate discovery explore autonomous science at ornl operations workforce powers ornl s autonomous science future read the full story q a with melissa cregger from field to factory with precision crops read the full story ornl researchers showcase ai driven science at national expo read the full story error correction tech boosts the 3d printing of big composite parts read the full story quantum advancing quantum science to unlock new capabilities in computing sensing and secure communication explore quantum at ornl ornl chattanooga startup accelerator partner to expand technology commercialization read the full story ornl deploys new iqm quantum computer read the full story calculating a new view on quantum mechanics using quantum computers read the full story researchers reprogram materials by quickly rearranging their atoms read the full story our strategy de risk deployment reducing the financial and technical risks of fission and fusion demonstration and deployment through innovation explore nuclear solutions isotopes advancing isotope science for a healthy secure and reliable future explore isotopes at ornl as californium 252 demand climbs ornl is increasing production read the full story world renowned radiopharmaceutical scientist to advance cancer therapies read the full story doe unveils breakthrough in domestic isotope supply chains read the full story first known computations of fusion materials on a quantum computer read the full story fission advancing fission to strengthen america s energy security and competitiveness explore fission at ornl advanced modeling accelerates nuclear energy read the full story fast tracking efficiency in light water reactor fuels read the full story small core big energy ornl led nuclear day engages students in stem read the full story a powerful pairing introduces new method of non destructive testing read the full story fusion harnessing the power of the stars to make commercial fusion energy a reality explore fusion at ornl ornl rev launch innovative collaboration on fusion infrastructure read the full story new innovation crossroads cohort tackles doe s toughest challenges read the full story prolific patenting sam hurst s legacy of invention at ornl read the full story small core big energy ornl led nuclear day engages students in stem read the full story our strategy modernization powering resilient affordable and secure energy systems for america explore resilient energy systems buildings building technologies for reliable and affordable energy explore buildings at ornl wagner awarded asme s 2026 henry laurence gantt medal read the full story ornl to feature transformative tech at arpa e summit read the full story oak ridge national laboratory launches the next generation data centers institute read the full story silva named a fellow of the american ceramic society read the full story grid building a smarter stronger u s electric grid explore grid at ornl modeling framework reveals grid battery aging effects read the full story wagner awarded asme s 2026 henry laurence gantt medal read the full story new ai enhanced tools detect electrical arcing reduce wildfires read the full story ornl developed cybersecurity framework graduates from lab to electric grid read the full story regional resilience uniting science and expertise to strengthen energy resilience and economic security explore regional resilience at ornl tapping water supply systems for energy production read the full story new ai enhanced tools detect electrical arcing reduce wildfires read the full story what 100 000 simulations reveal about our power grid read the full story ai model delivers river temperature insights strengthening us energy security read the full story transportation strengthening the technologies and systems that move people goods and energy across the nation explore transportation at ornl novel high temperature alloys enable lighter more fuel efficient truck engines read the full story ornl partnership helps acp technologies scale materials for graphite and carbon fiber read the full story ornl earns five doe transportation technologies office awards read the full story new motor drive design reduces heat wear in high power systems read the full story ornl overview discover the mission history leadership and values that guide ornl s work keep exploring watch the video explore our history who we are faqs operations explore how operational excellence guides the way we plan perform and improve our work at ornl as we take on some of the nation s most important scientific and technical challenges explore operations partnerships find the partnership opportunities expertise and capabilities to help move your ideas forward explore all partnership opportunities explore technologies available to license for entrepreneurs economic development strategic partnerships november 2023 journal pd metalated conjugated nanoporous polycarbazoles for additive free cyanation of aryl halides boosting catalytic efficiency through spatial modulation by ding shunmin tian chengcheng zhu xiang abney carter w tian ziqi chen bo li meijun jiang de en zhang ning dai sheng journal name chemsuschem page number 2348 2351 volume 10 issue number 11 publication date november 2023 view doi listing https doi org 10 1002 cssc 201700329 abstract a novel spatial modulation approach was developed to fabricate a new heterogeneous pd metalated nanoporous polymer for efficient and ligand free cyanation of aryl halides the resulting catalyst displays high activity in the synthesis of benzonitriles including high product yield excellent stability and recycle and broad scope functional group tolerance related researchers sheng dai oak ridge national laboratory 1 bethel valley road oak ridge tn 37830 1 865 576 7658 news news desk newsletter signup media resources research research areas user facilities resources internal users directory connect partnerships visit contact oak ridge national laboratory is managed by ut battelle llc for the us department of energy privacy security notice accessibility 508 nondiscrimination 1557 vulnerability disclosure program cancel search
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